- PII
- 10.31857/S0869780925010088-1
- DOI
- 10.31857/S0869780925010088
- Publication type
- Article
- Status
- Published
- Authors
- Volume/ Edition
- Volume / Issue number 1
- Pages
- 75-86
- Abstract
- Contamination of shallow aquifers and rocks in the vadose zone with oil and its refined products is one of the most common types of technogenic pollution of the geological environment. Specifics of infrastructure development of territories require the compact location of enterprises engaged in the storage and transportation of petroleum products belonging to different business entities. When carrying out engineering and environmental survey, it is important not only to outline the contamination plume in plan and by geological cross-section, but also to identify correctly the sources of oil products entering the subsurface. To solve this problem, an approach was proposed based on comparing data on the chemical composition of oil products samples from prospecting boreholes. It is proposed to normalize chemical analysis data using a common and clearly distinguishable peak for all chromatograms. The approach was tested on the oil-polluted site. Comparison of chromatograms allows identifying the affiliation of petroleum products to different sources of pollution even if they are of the same type and have close average molecular weights. The results of the studies made it possible to prove the multiplicity of pollution sources (at least 4). The main directions of pollution transformation are the loss of light hydrocarbons and aromatic compounds as a result of their evaporation, dissolution in groundwater and biodegradation.
- Keywords
- нефть нефтепродукты загрязнение подземных вод химический состав водоносный горизонт разведочная скважина топливные отпечатки пальцев
- Date of publication
- 19.09.2025
- Year of publication
- 2025
- Number of purchasers
- 0
- Views
- 10
References
- 1. Корнеева Е.А., Авсюкевич А.П., Кудрявцев А.В. Изыскания и ликвидация загрязнений грунтовых вод // Промышленное и гражданское строительство. 2022. №5. С. 31-37.
- 2. Мироненко В.А., Петров Н.С. Загрязнение подземных вод углеводородами // Геоэкология. 1995. №1. С. 3-27.
- 3. Мироненко В.А., Румынин В.Г. Проблемы геоэкологии. Т. 3. Кн. 2. М.: Недра, 2002. 504 с.
- 4. Пинчук Н.П., Юнак А.И., Покутник А.С., Хархордин И.Л. и др. Изучение и очистка водоносных горизонтов и зоны аэрации, загрязненных нефтепродуктами (Аналитический обзор). М.: НИА-Природа, 2002. 48 с.
- 5. Товарные нефтепродукты, их свойства и применение. Справочник / Под ред. Н.Г. Пучкова. М.: Химия, 1971. 415 с.
- 6. Хархордин И.Л., Абрамов В.Ю., Потапов А.А., Блинов К.В. Загрязнение р. Невы нефтепродуктами, поступающими с подземным стоком // Разведка и охрана недр. 1998. №7-8. С. 71-73.
- 7. Alimi H., Ertel T., Schug B. Fingerprinting of Hydrocarbon Fuel Contaminants: Literature Review // Environmental Forensics. 2003. No. 4. P. 25-38.
- 8. Bhuparthiraju V.K., Krauter P., Holman H.-Y. N. et al. Assessment of in-situ bioremediation at a refinery waste-contaminated site and an aviation gasoline contaminated site // Biodegradation. 2002. V. 13. P. 79-90.
- 9. Borden R.S., Bedient P.B. Transport of dissolved hydrocarbons influenced by oxygen-limited biodegradation. 1. Theoretical development // Water Resources Research. 1986. V. 22. No. 13. P. 1973-1982.
- 10. Faust C.R. Transport of immiscible fluids within and below unsaturated zone: A numerical model // Water Resources Research. 1985. V. 21. No. 4. P. 587-596.
- 11. Hunt J.R., Sitar N., Udell K.S. Nonaqueos phase transport and cleanup. Analysis of mechanisms // Water Resources Research. 1988. V. 24. No. 8. P. 1247-1258.
- 12. Karickhoff S.W. Organic pollutant sorption in aquatic system // Journal of Hydraulic Engineering. 1979. V. 110. No. 6. P. 707-735.
- 13. Lenhard R.J., Parker J.C. Estimation of free product hydrocarbon volume from liquid levels in monitoring wells // Ground Water. 1990. V. 28. P. 57-67.
- 14. Mackay D.L., Cherry J.A. Groundwater contamination: pump-and-treat remediation // Environmental Science & Technology. 1989. V. 23. No. 6. P. 620-636.
- 15. Marrin D.L. Soil-gas sampling and misinterpretation // Groundwater Monitoring & Remediation. 1988. Spring. P. 51-54.
- 16. Mercer I.W., Cohen R.M. A review of immiscible fluids in the subsurface: properties, models, characterization and remediation // Journal of Contaminant Hydrology. 1990. No. 6. P. 107-163.
- 17. Washington J.W. Gas partitioning of dissolved volatile organic compounds in the vadose zone: principles, temperatures effects, and literature review // Ground Water. 1996. V. 34. No. 4. P. 709-718.